Redox-responsive colloidosomes via supramolecular chemistry
| dc.contributor | Graduate Program in Chemistry. | |
| dc.contributor.advisor | Sanyal, Amitav. | |
| dc.contributor.author | Helvacı, Hasan Can. | |
| dc.date.accessioned | 2023-03-16T11:00:31Z | |
| dc.date.available | 2023-03-16T11:00:31Z | |
| dc.date.issued | 2015. | |
| dc.description.abstract | In supramolecular chemistry, molecules can be assembled together through non-covalent interactions without management from an outside source in order to form well-organized structures such as micelles, microspheres, interface (membrane) or colloidal microcapsules. This thesis focused on formation and stabilization of self-assembled microcapsules by using host-guest interaction, encapsulation biomolecules into these microcapsules and controlled released of them after the microcapsules exposed to reducing agent. In this study, β-cyclodextrin functionalized gold nanoparticles were used as host molecules and bis-adamantane containing linker molecules and adamantine functionalized iron oxide nanoparticles were used as guest molecules. Due to strong interaction between adamantine and β-cyclodextrin molecules, stable microcapsules were obtained as a result of cross-linking host and guest molecules at water-organic interfaces of emulsions. Then the disassembly of microcapsules was analyzed after exposure to reducing agent. Resulting microcapsules were characterized using a variety of techniques such as optical microscopy, fluorescence microscopy, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). | |
| dc.format.extent | 30 cm. | |
| dc.format.pages | xvii, 62 leaves ; | |
| dc.identifier.other | CHEM 2015 H46 | |
| dc.identifier.uri | https://digitalarchive.library.bogazici.edu.tr/handle/123456789/14332 | |
| dc.publisher | Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2015. | |
| dc.subject.lcsh | Supramolecular chemistry. | |
| dc.title | Redox-responsive colloidosomes via supramolecular chemistry |
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