Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds

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dc.contributorGraduate Program in Chemistry.
dc.contributor.advisorBulak, Ece.
dc.contributor.authorÜnal, A. Özge Akdeniz.
dc.date.accessioned2023-03-16T11:00:29Z
dc.date.available2023-03-16T11:00:29Z
dc.date.issued1999.
dc.description.abstractIn this study the reaction of 16 e- system, dichlorobiscyclopentadienyl- zirconium(IV) with N-containing, S-containing and thioamide containing ligands were studied. In the presence of a non-coordinating solvent, CH2Cl2, thioacetamide coordinated to Cp2ZrCl2 through C=S unit with participation of the NH group. This complexation was proved by the new bands appearing in Zr-N and Zr-S stretching region, also by the blue shift of thioamide band I and the red shift of thioamide band IV of thioacetamide. Deprotonated ethanethiol with Cp2ZrCl2 gave a dimeric complex with the formula (Cp2ZrClSCH2CH3)2. Without deprotonation ethanethiol did not coordinate to Cp2ZrCl2.
dc.format.extent30 cm.
dc.format.pagesxv, 76 leaves;
dc.identifier.otherCHEM 1999 Un11
dc.identifier.urihttps://digitalarchive.library.bogazici.edu.tr/handle/123456789/14327
dc.publisherThesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 1999.
dc.subject.lcshHeterocyclic compounds.
dc.titleReactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds

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